Perylene-Based Bis-, Tetrakis-, and Hexakis(terpyridine) Ligands and Their Ruthenium(II)-Bis(terpyridine) Complexes: Synthesis and Photophysical Properties
β Scribed by El-Batal, Hany; Guo, Kai; Li, Xiaopeng; Wesdemiotis, Chrys; Moorefield, Charles N.; Newkome, George R.
- Book ID
- 120307073
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 602 KB
- Volume
- 2013
- Category
- Article
- ISSN
- 1434-193X
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## Abstract [2]Rotaxanes based on the 1,2βbis(pyridinium)ethaneβ[24]crownβ8 ether motif were prepared that contain a terminal terpyridine group for coordination to a transitionβmetal ion. These rotaxane ligands were utilized in the preparation of a series of heteroleptic [Ru(terpy)(terpyβrotaxane)]
Four diads consisting of a free-base or zinc aryl-porphyrin associated with two ruthenium(II) bis(terdentate) complexes (non-cyclometallated Ru ( N 6) or cylometallated Ru ( N 5 C )) have been synthesized. The strong electron-withdrawing properties of the Ru ( N 6) as compared to the Ru ( N 5 C ) co
## Abstract For Abstract see ChemInform Abstract in Full Text.