Perturbation method for phase-equilibrium calculations
β Scribed by E. M. Hendriks
- Publisher
- Springer
- Year
- 1989
- Tongue
- English
- Weight
- 567 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0195-928X
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## Abstract The equalβarea (EA) method is studied with respect to its applicability to a wide range of phase equilibrium scenarios for pure fluids and binary mixtures. The study covers vaporβliquid equilibrium (VLE), liquidβliquid equilibrium (LLE), solidβliquid equilibrium (SLE) and their crossove
A general method to calculate the deviation from local equilibrium at phase interfaces in multicomponent systems is suggested. The deviation is caused by solute drag and finite interfacial mobility. In the limit of low transformation rates the new method degenerates to the well-known local equilibri