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Perturbation-enhanced quenching of laser-excited CS A1π(ν = 0) by atomic oxygen

✍ Scribed by A.J. Hynes; J.H Brophy


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
417 KB
Volume
75
Category
Article
ISSN
0009-2614

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✦ Synopsis


Quenchmg of CS A 'n(v = 0) by 0 3P IS enhanced by perturbations due to a' 3 Z+(u = 10) and d 3A (u = 4) The rotatlonal-state dependence IS lmcar UI the s&et-trIplet m~vmg coefficients and mdlcates an orrentatlondependent mteractlon Symmetry correlations suggest that the perturbations promote formation of an attractive coksion complex with quenching by intersystem crossmg or chcnucal reaction