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Perturbation calculation of transition moments in the ArH+ system

✍ Scribed by G. Chambaud; B. Levy; Ph. Millié

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
279 KB
Volume
18
Category
Article
ISSN
0020-7608

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✦ Synopsis

Abstract

The matrix elements of the transition dipolar momentum IR have been computed between the low‐lying states associated to the Lyman–α transition. The orthogonalization of the involved electronic states (obtained by the CIPSI method) has been performed and led to a better value for the asymptotic behavior of the {Ar(3__p__^5^, 4__s__) + H^+^} configuration. Position of the satellites in the red and blue wing of the line are deduced from the potential‐energy curves in the frame of the quasistatic theory.

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