## Abstract Published theoretical equations for the sedimentation coefficient and intrinsic viscosity of a semiflexible chain are compared, neglecting the excluded volume effect. The theories are extended to the case of a small excluded volume, by applying the perturbation theory, established for f
Persistence lengths of semiflexible chains — methods and approximations
✍ Scribed by Matthias Otto; Jochen Eckert; Thomas A. Vilgis
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 567 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1022-1344
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Several models and methods for stiff polymer chains are discussed. The basic idea is to develop approximate solutions to the problem of the presistence length of stiff polymers. It turns out that the persistence length can be regarded as a measure for the quality of approximations. Mean‐field methods for field theoretical calculations of the persistence length show similarities of 1/d expansions in statistical physics (d being the space dimension) and saddle point approximations become reliable in various limits. Gaussian approximations become — as well known for the Ising model — simple extensions of random walks as trivial renormalisations of the Wiener‐Edwards model for bosonic strings.
📜 SIMILAR VOLUMES
## Abstract Monte Carlo simulations were carried out to investigate the adsorption of semiflexible chains from a semidilute solution to substrates with periodic stripes of width __w__. The chains are made of fused __N__ = 10 monomers of diameter __σ__ interacting with each other through excluded vo
## Abstract A range of polyamides has been modelled using Monte Carlo routines based on carefully determined bond‐rotation potentials, bond length and bond angle. For each polymer type, a large number of chains has been built for different simulated temperatures, and the persistence lengths determi
## Abstract The distribution function __P__(__S__) of the radius of gyration __S__, the corresponding elastic free energy __A__(__S__) and the mean force $\left\langle f \right\rangle (S)$ were computed from simulations based on the wormlike chain (WLC) model. The relation of the __S__‐conjugated e