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Persilylated Phosphoranyl Radicals: The First Persistent Noncyclic Phosphoranyl Radicals

โœ Scribed by Yves Berchadsky; Christiane Bernard-Henriet; Jean-Pierre Finet; Robert Lauricella; Sylvain R. A. Marque; Paul Tordo

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
309 KB
Volume
12
Category
Article
ISSN
0947-6539

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๐Ÿ“œ SIMILAR VOLUMES

31P CIDNP in the reactions of phosphoran
31P CIDNP in the reactions of phosphoranyl radicals
โœ Ya. A. Levin; A. V. Il'yasov; E. I. Goldfarb; E. I. Vorkunova ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 419 KB

## Abstract The polarisation of phosphorus nuclei (^31^P CIDNP) during the free radical reactions of triakyl and triaryl phosphites proceeding via intermediate phosphoranyl radicals is discussed.

The structure and hyperfine splittings o
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โœ A. Hudson; R.F. Treweek ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 161 KB

The ab initio UHF method has been employed to calculate equilibrium geometries and isotopic hype&&e coupling ccnstantsfor the radicals PHI, PFa, PH4 and PF4.

Where is the unpaired electron in the ph
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โœ Christopher J. Cramer ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 504 KB

High-level, correlated electronic structure calculations on H,PS-and HsPSH indicate these two radicals to adopt trigonal bipyramidal geometries in which the unpaired electron is localized equatorially, although for the neutral species only the equatorially oriented mercaptan is stable to P-S bond ho

UHF CNDO/2 study of the phosphoranyl rad
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โœ Y.I. Gorlov; V.V. Penkovsky ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 362 KB

The equilibrium geometries and spin density distributions for some phosphoranyl radicals and the radical anion PH30were calculated by the UHF CNDO/2 method. Barriers to permuhtional isomerization in PFQ and PHsOH were estirxted.