The kinetics of aqueous polymerization of acrylamide (AM) and methacrylamide (MAM) have been studied using a potassium peroxydiphosphate (PDP/Mn(II) system in an inert atmosphere at 40ยกC and at constant pH (1ร30). The polymerization rate has been found to be proportional to the half power R p of PDP
โฆ LIBER โฆ
Peroxydiphosphate/bisulfite-initiated polymerization of acrylamide and its retardation kinetics
โ Scribed by U. D. N. Bajpai; A. K. Bajpai; J. Bajpai
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 498 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0021-8995
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Acrylamide was polymerized in acetonitrile at 82 ยฐC with a perfluorinated azo-derivative initiator. The polymerization proceeded heterogeneously. Varying amounts of initiator and monomer were used. The activation energy was deduced from three experiments carried out at 59, 71, and 82 ยฐC. The followi