Peroxy radicals from night-time reaction of N03 with organic compounds
β Scribed by Platt, U.; LeBras, G.; Poulet, G.; Burrows, J. P.; Moortgat, G.
- Book ID
- 109766410
- Publisher
- Nature Publishing Group
- Year
- 1990
- Tongue
- English
- Weight
- 436 KB
- Volume
- 348
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/348147a0
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The yields of C, and C, alkyl nitrates from neopentane, 2-methylbutane, 2-methylpentane, 3-methylpentane, and cyclohexane have been measured in irradiated CH30NO-NO-alkane-air mixtures at 298 t-2 K and 735-torr total pressure. Additionally, OH radical rate constants for neopentyl nitrate, 3-nitro-2-
## Abstract A flash photolysis setup coupled to UV absorption spectrometry detection was used to measure the UV absorption spectra of the (CH~3~)~2~(CH~2~O~2~.)CC(O)C(CH~3~)~3~ and (CH~3~)~2~(CH~2~O~2~.)CC(O)CH~3~ radicals between 207 and 290 nm. The selfβreaction rate constants of these radicals w