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Peroxopolyoxometalate-based room temperature ionic liquid as a self-separation catalyst for epoxidation of olefins

✍ Scribed by Huan Li; Zhenshan Hou; Yunxiang Qiao; Bo Feng; Yu Hu; Xiangrui Wang; Xiuge Zhao


Book ID
118427234
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
357 KB
Volume
11
Category
Article
ISSN
1566-7367

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✍ Loubna Gharnati; Olaf Walter; Ulrich Arnold; Manfred DΓΆring πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 434 KB

## Abstract Several penta‐ and hexaalkylated guanidinium‐based ionic liquids (GILs) were tested as solvents for the epoxidation of cyclooctene using the Venturello catalyst, [(C~8~H~17~)~3~N(CH~3~)]~3~[PO~4~{WO(O~2~)~2~}~4~], and hydrogen peroxide as the oxidant. Epoxide yields were obtained in a b