Peroxo complexes of molybdenum and tungsten stabilized by oxides of amines, phosphines, and arsines. Stability studies
โ Scribed by Westland, Alan D.; Haque, Ferial; Bouchard, Jean Marc
- Book ID
- 121420780
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 673 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0020-1669
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The 13C NMR spectra of a series of Pd" complexes containing phosphine, arsine and amine ligands, have been measured. The 13C chemical shift of the carbon atom adjacent to the donor atom, and the paracarbon in corresponding phenyl derivatives can be useful probes for the determination of complex geom
The oxidation of organic compounds by hydrogen peroxide, catalysed by transition metal derivatives, e.g. V(V), Mo(V1) and W (VI) complexes, involves the formation of peroxometal complexes. These are much more efficient oxidants than hydrogen peroxide so that the catalysed reactions are of remarkable