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Peroxo and superoxo copper complexes: Electronic structure contributions to reactivity

✍ Scribed by David E. Root; Narashima N. Murthy; Kenneth D. Karlin; Nobumasa Kitajima; Kiyoshi Fujisawa; Yoshihiko Moro-oka; Edward I. Solomon


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
72 KB
Volume
59
Category
Article
ISSN
0162-0134

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The tetrapodal pentaamine ligand 2,6-bis(1Ј,3Ј-diamino-2Јmethylprop-2Јyl)pyridine (pyN 4 , 1) provides square-pyramidal coordinated cobalt(II) building blocks, which have been used in the synthesis of the singly-bridged dicobalt(III) ¡ 2η 1 :η 1 -peroxo and superoxo complexes [(1)Co-O 2 -Co(1)] 4+/5