Peroxide/Potassium Iodide Redox Systems for in situ Oxyiodination of Organic Compounds under Liquid-Phase and Solvent-Free Conditions

✍ Scribed by Gattu Venkateshwarlu; Akarapu Premalatha; Anuganti Chakradhar; Kamatala Chinna Rajanna; Pondichery Kuppuswamy Sai Prakash

• Book ID: 102253737
• Publisher: John Wiley and Sons
• Year: 2010
• Tongue: German
• Weight: 139 KB
• Volume: 93
• Category: Article
• ISSN: 0018-019X
• DOI: 10.1002/hlca.200900188

✦ Synopsis

Abstract

Iodination of certain aromatic amines and phenols are triggered by the oxidation of KI by peroxy compounds such as tert‐butyl hydroperoxide (^t^BuOOH) under liquid‐phase and solvent‐free conditions by grinding the reactants in a mortar with a pestle. The reactions afforded corresponding iodo derivatives in good yield with high regioselectivity (Table 1).