✦ LIBER ✦

Peroxide-initiated grafting of maleic anhydride onto linear and branched hydrocarbons

✍ Scribed by S. Ranganathan; W. E. Baker; K. E. Russell; R. A. Whitney

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 173 KB
Volume: 37
Category: Article
ISSN: 0887-624X
DOI: 10.1002/(sici)1099-0518(19991015)37:20<3817::aid-pola10>3.0.co;2-v

No coin nor oath required. For personal study only.

✦ Synopsis

The structural features of the grafting of maleic anhydride onto low-molecular-weight compounds have been elucidated using several spectroscopic and analytical techniques. Conclusive evidence for the occurrence of singly grafted anhydride residues in multiply grafted products has been established using 2,3-13 C 2 labeled maleic anhydride. In homogeneous solution, at the low concentrations of maleic anhydride employed, there is little evidence for oligomeric or polymeric grafts to dodecane, pristane, or squalane. The results suggest that isothermal grafting of maleic anhydride to hydrocarbon polymers should also lead to a predominance of single grafts.

📜 SIMILAR VOLUMES

Peroxide-initiated comonomer grafting of

Peroxide-initiated comonomer grafting of styrene and maleic anhydride onto polyethylene: Effect of polyethylene microstructure

✍ D. C. Clark; W. E. Baker; R. A. Whitney 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 195 KB 👁 2 views

Dual monomer grafting of styrene and mal

Dual monomer grafting of styrene and maleic anhydride onto model hydrocarbon substrates

✍ D. C. Clark; W. E. Baker; K. E. Russell; R. A. Whitney 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 210 KB 👁 2 views

Styrene and maleic anhydride (MAn) were successfully grafted, alone and simultaneously, onto various model hydrocarbon substrates at 180 °C with 2,5-dimethyl-2,5-di-(t-butyl peroxy)hexane (L101) as a free-radical initiator. Dodecane, 1-dodecene, and 2,6,10,14-tetramethylpentadecane were selected as

Grafting of maleic anhydride onto polypr

Grafting of maleic anhydride onto polypropylene: Synthesis and characterization

✍ Sachin N. Sathe; G. S. Srinivasa Rao; Surekha Devi 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 421 KB 👁 1 views

## SYNOPSIS Isotactic polypropylene was grafted with maleic anhydride using benzoyl peroxide as an initiator and toluene as a solvent. Effects of various parameters such as monomer and initiator concentration, reaction time, and reaction temperature on percentage grafting were studied. Effect of v

Grafting of maleic anhydride onto polypr

Grafting of maleic anhydride onto polypropylene by reactive processing. I. Effect of maleic anhydride and peroxide concentrations on the reaction

✍ S. H. P. Bettini; J. A. M. Agnelli 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 194 KB 👁 2 views

Grafting reactions were performed in a Haake torque rheometer, according to a central composite experimental design, where the maleic anhydride and peroxide concentrations, rotor speed, and reaction time were varied. The 27 formulations were analyzed by Fourier transformed infrared spectroscopy and

Peroxide initiated maleic anhydride graf

Peroxide initiated maleic anhydride grafting: Structural studies on an ester-containing copolymer and related substrates

✍ S. Ranganathan; W. E. Baker; K. E. Russell; R. A. Whitney 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 224 KB 👁 1 views

Maleic anhydride (MAn) was grafted onto the low molecular weight esters methyl decanoate (MD) and methyl 2-ethylhexanoate (MEH) using the free-radical initiators Lupersol-101 and -130; the esters were used as model compounds for the copolymer poly(ethylene-co-methyl acrylate). The grafted products i

Grafting of maleic anhydride onto carbon

Grafting of maleic anhydride onto carbon black surface via ultrasonic irradiation

✍ Xiaojun Zhou; Qiuying Li; Chifei Wu 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 196 KB 👁 1 views