Peroxidase-Catalyzed Oxidative Polymerization of Phenol with a Nonionic Polymer Surfactant Template in Water
✍ Scribed by Young-Jin Kim; Hiroshi Uyama; Shiro Kobayashi
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 143 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1616-5187
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✦ Synopsis
Abstract
Summary: Peroxidase‐catalyzed oxidative polymerization of phenol has been examined using the template, poly(ethylene glycol) monododecyl ether (PEGMDE), in water. The role of this template, which forms a complex with phenol in the polymerization, was verified by UV measurements. During the reaction, a complex of the resulting polymer and PEGMDE was precipitated in high yields. The amount and the PEG chain length of PEGMDE strongly affected the polyphenol yield. The unit molar ratio of polyphenol and PEG of the template was about 1:0.9. The presence of the PEGMDE template in the aqueous medium greatly improved the regioselectivity of the polymerization, yielding polyphenol with a phenylene unit content close to 90%. FT‐IR, DSC, and XRD analyses confirmed the formation of the miscible complex of polyphenol and PEGMDE by hydrogen‐bonding interactions.
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