The effect of internal diffusion on dehydration of methanol on model pellets of porous catalyst (sulfonated stymm-divinylbenzene ion exchange resin) was studied experimentally. The results proved that bulk diffusion of a multicomponent reaction mixture in a porous catalyst can be satisfactorily desc
Permeation of gases in industrial porous catalysts
✍ Scribed by Pavel Čapek; Vladimı́r Hejtmánek; Olga Šolcová
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 120 KB
- Volume
- 81
- Category
- Article
- ISSN
- 1385-8947
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✦ Synopsis
An experimental method for determination of porous solid texture was proposed and verified. The method is based on unsteady permeation of single gases in a porous medium. Transport parameters characterizing porous materials were determined by fitting the experimental data to the theoretical transient responses by minimizing the objective function. Confidence limits of the transport parameters were evaluated on the base of the Beale criterion. Results were discussed in terms of different mechanisms of mass transport. Advantages of this technique were demonstrated for three porous catalysts of different textures.
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Steady-state permeation rates for pure COz and CH4 and the binary mixture through homogeneous dense polysulfone and polycarbonate membranes have been measured at 40°C and upstream pressures up to 26 atm. The pressure dependence of the mean permeability coefficients for COz and CH, for all of the sys