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Permanganate ion oxidation of thymine: Spectrophotometric detection of a stable organomanganese intermediate

✍ Scribed by Fillmore Freeman; Charles Orise Fuselier; Elaine Marie Karchefski

Book ID: 104215219
Publisher: Elsevier Science
Year: 1975
Tongue: French
Weight: 202 KB
Volume: 16
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)75315-9

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✦ Synopsis

Permanganate ion quantitatively oxidizes 5-methyl-2,4(1H, 3H)-pyrimidinedione C thymine, (i) ] in phosphate buffered solutions to varying proportions of e-5,6dihydroxy-5,6dihydrothymine (2J and 5-hydroxy-5-methylbarbituric acid (3_,.2 The ratio 2:2_is pH dependent, and z predominates in alkaline media. The stability of 2, under the rl, il iI

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