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Periodic Positioning of Multilayered [2.2]Paracyclophane-Based Nanopillars

✍ Scribed by David Bléger; David Kreher; Fabrice Mathevet; André-Jean Attias; Imad Arfaoui; Germain Metgé; Ludovic Douillard; Céline Fiorini-Debuisschert; Fabrice Charra

Book ID
102728197
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
695 KB
Volume
47
Category
Article
ISSN
0044-8249

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Tricarbonylchromium complexes of cyclophanes have been studied to demonstrate transannular electronic interaction between the aromatic rings in the ligand cyclophanes.2' In a series of tricarbonylchromium complexes of [m.n]-

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A new ortho-lithiation of homochiral 4-N,N-diethylamido[2.2]paracyclophane 8 is the key to the production of a wide variety of 4,5-disubstituted homochiral ligands. c-Geminal bromination of 8 proceeds in high yields and the resulting bromide may be converted into a variety of 4,13-disubstituted liga