Performance of γ-alumina-supported Wacker catalysts in the oxidation of 1-butene
✍ Scribed by A.W. Stobbe-Kreemers; M. Soede; M. Makkee; J.J.F. Scholten
- Book ID
- 103965794
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 957 KB
- Volume
- 131
- Category
- Article
- ISSN
- 0926-860X
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Palladium salts of heteropolyanions, of the Keggin-series H3+ nPVnMol2\_nO40, supported on silica, have been successfully applied as catalysts in the gas-phase Wacker oxidation of 1-butene. In such catalysts the palladium reaction centre (Pd 2+ ) and the redox component (HPA) are combined in one com
Volcano-type patterns, not only in methane conversion but also in C x + hydrocarbons' selectivity, were observed over 60 wt.-% of PbO loaded on y-alumina. The maximum population of PbAl\*O, spine1 phase, considered to be formed due to the diffusion of Pb\*+ as well as A13+ and O\*-ions, was obtained