Performance of solid oxide fuel cells based on proton-conducting BaCe0.7In0.3-xYxO3-δ electrolyte
✍ Scribed by Fei Zhao; Fanglin Chen
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 800 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0360-3199
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✦ Synopsis
The performances of solid oxide fuel cells with proton conductors BaCe 0.7 In 0.3Àx Y x O 3Àd (BCIY, x ¼ 0, 0.1, 0.2, 0.3) as electrolytes were investigated in this work. The cell based on BaCe 0.7 In 0.2 Y 0.1 O 3Àd electrolyte showed maximum power outputs of 0.114, 0.204 and 0.269 Wcm À2 at 600, 650 and 700 C, respectively. After operating at a constant cell voltage output of 0.5V for 40h, no obvious degradation in performance was observed for the cells based on BaCe 0.7 In 0.3 O 3Àd and BaCe 0.7 In 0.2 Y 0.1 O 3Àd electrolytes. However, although relatively lower resistances and higher initial power outputs were found for cells based on BaCe 0.7
In 0.1 Y 0.2 O 3Àd and BaCe 0.7 Y 0.3 O 3Àd electrolytes, rapid cell performance degradations were observed for these two cells. The stability under cell operating conditions remained a challenge for cells using BaCe 0.7 In 0.1 Y 0.2 O 3Àd and BaCe 0.7 Y 0.3 O 3Àd electrolytes.
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## Abstract Dense proton‐conducting BaZr~0.1~Ce~0.7~Y~0.2~O~3 – δ~ (BZCY) electrolyte membranes were successfully fabricated on NiO–BZCY anode substrates at a low temperature of 1,150 °C __via__ a combined co‐press and co‐firing process. To fabricate full cells, the LaSr~3~Co~1.5~Fe~1.5~O~10 – δ~–B