Abstract
BACKGROUND: Cellular foam materials are a new type of catalyst support that provides improved mass and heat transport characteristics and similar pressure drops to other well‐established structured supports such as monoliths.
RESULTS: A Pd‐based catalyst has been prepared using a moderate surface area (25 m^2^ g^−1^) β‐SiC foam support without further washcoating. The stability of this catalyst has been tested for methane combustion at lean conditions, showing a small decrease of activity during the first 10 h followed by stable performance. Characterization of fresh and aged catalyst shows no significant changes. The influence of the most important reaction conditions, such as reactor loading (0.25–1 g), temperature (300–550 °C) and inlet methane concentration (833 and 1724 ppm), was studied in a fixed‐bed reactor. The results were fitted to three kinetic models: Mars‐van Krevelen; Langmuir‐Hinselwood; power‐law kinetics.
CONCLUSIONS: The Pd/β‐SiC foam catalyst, prepared without the previous addition of a washcoating has been demonstrated to be stable for the combustion of methane‐air lean mixtures. A Mars‐van Krevelen kinetic model provides the best fit to the results obtained. Copyright © 2011 Society of Chemical Industry