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Perfluoro-enolate chemistry: An “electrophile-coexisting” procedure for carbon-carbon bond forming reactions with an ester lithium f-enolate

✍ Scribed by Cheng-Ping Qian; Takeshi Nakai


Book ID
104228531
Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
222 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis


A novel "electrophile-coexisting" procedure is developed for effecting aldol reactions and Michael additions with the lithium F-enolate of ethyl tetrafluoropropionate without appreciable occurrence of defluorination from the F-enolate.