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Perfluoro effects in 15N nuclear magnetic resonance spectroscopy. Part 1. Aryl and N-heteroaryl azides

✍ Scribed by Kanjia, D. Magan; Mason, Joan; Stenhouse, Ian A.; Banks, Ronald E.; Venayak, Narinder D.

Book ID
120556247
Publisher
Royal Society of Chemistry
Year
1981
Tongue
English
Weight
536 KB
Volume
6
Category
Article
ISSN
1472-779X

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Nitrogen-15 nuclear magnetic resonance spectroscopy. 15N19F coupling constants in fluoropyridines and fluoroanilines
✍ Mukund P. Sibi; Robert L. Lichter πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 English βš– 298 KB

## Abstract Two‐to five‐bond ^15^Nο£Ώ^19^F coupling constants have been determined for fluoropyridines, 8‐fluoroquinoline, fluoroanilines and fluoroaniline derivatives. Only in 2‐fluoropyridine is __J__(NF) large, and this is associated with a lone pair mediated enhancement of the coupling. Values in