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Perfluoro-1,2-diisopropylidene-3,3-dimethylcyclobutane — A new cross-conjugated perfluorotriene isomer

✍ Scribed by E. G. Ter-Gabrielyan; N. P. Gambaryan


Book ID
112446487
Publisher
Springer
Year
1986
Tongue
English
Weight
301 KB
Volume
35
Category
Article
ISSN
1573-9171

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2-Trimethylsilylethyl-1,3-butadiene, readily prepared by the cross-coupling reaction of the Grignard reagent of 3-bromo-3-butenyltrimethylsilane with vinyl bromide catalyzed by a nickel-phosphine complex, works as a synthetic equivalent to 3-methylene-1,4-pentadiene (parent [3ldendralene) by the con