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Perchloric acid flames VII-mixed fuel-rich flames

✍ Scribed by G.S. Pearson


Book ID
103040788
Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
785 KB
Volume
11
Category
Article
ISSN
0010-2180

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✦ Synopsis


Fuel-rich perchloric acid flames containing binary mixtures of hydrocarbons (methane-ethane, methane-:thylene and ethane-¢thylcnO as fads have hen studied by sampling the burnt gas products for a range of mixtures of each pair of flkel,~, it ha,~ been shown that there is selective consumption of one member of each fuel pair and tht~t t~le order of increasing resistance to attack is ethane < ethylene < methane. Approximate ratios of the rate constants for the attack on the fuels are deduced and compared with the literature values for hydrogen, oxygen and ,:hlorine atom and hydroxyl radical attack on the same hydrocarbons. It is concluded that the results obtained here provide additional support for a mechanism involving chlorine-oxygen species.

* Copi~ o~ diavams showin~ the~ burnt gas con~'ntralions and also of the burning vd.~ities are available from the author.


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