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Peracid oxidation of imines. Kinetics and mechanism of competitive formation of nitrones and oxaziranes from cyclic and acyclic imines

✍ Scribed by Ogata, Yoshiro.; Sawaki, Yasuhiko.


Book ID
126288630
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
897 KB
Volume
95
Category
Article
ISSN
0002-7863

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Kinetics and mechanism of the oxidation
✍ Basudeb Saha; Amitava Dutta; Sumana Gangopadhyay; Pradyot Banerjee πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 115 KB πŸ‘ 2 views

The kinetics of the oxidation of formate, oxalate, and malonate by [Ni III (L 1 )] 2ϩ (where HL 1 ϭ 15-amino-3-methyl-4,7,10,13-tetraazapentadec-3-en-2-one oxime) were carried out over the regions pH 3.0 -5. 75, 2.80 -5.50, and 2.50 -7.58, respectively, at constant ionic strength and temperature 40Њ