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Peracid oxidation of 2,4-dimethyl-3-ethylpyrrole (Kryptopyrrole)

โœ Scribed by Josefina Awruch; Benjamin Frydman


Book ID
104247090
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
220 KB
Volume
14
Category
Article
ISSN
0040-4039

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Facile synthesis of 3,4-dihydro-4,4-dime
โœ Mariko Tanaka; Hisao Urata; Takamasa Fuchikami ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 244 KB

Selective terminal oxidation of 3,3-dimethyl-4-pentenoates does occur under chloride-free Wacker conditions [Pd(OAc)2/02] in AcOH to give 5-acetoxy-3.3-dimethyl-4pentenoates ( 7) and their analogues (2. 8) in good yields. Successive cyclization of 7 and 8 at vapor phase pyrolysis on SiO2 affords '3,