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Peracid induced ring opening of some isoxazolidines and oxidation of saturated 1,3-oxazines to new heterocyclic nitrones

โœ Scribed by Syed M.A. Hashmi; Sk.Asrof Ali; Mohammed I.M. Wazeer


Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
682 KB
Volume
54
Category
Article
ISSN
0040-4020

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Cycloaddition/Ring Opening of 3-Unsubstituted Cyclic Nitronates, Isoxazoline and 5,6-Dihydro-4H-1,2-oxazine N-Oxides, as Synthetic Equivalents of Functionalized Nitrile Oxides. -Treatment of 3-halo-1-nitropropane [cf. (I)] with base results in cyclization to a nitronate. Trapping with electron-rich