## Abstract A new photocatalyst, named TiO~2~ microspheres, prepared by a sol‐spraying‐calcination method, can freely suspend with air bubbling in its aqueous suspension and easily settle down from a water phase under gravity. The experimental results demonstrated that TiO~2~ microspheres had bette
Peracetic acid-enhanced photocatalytic and sonophotocatalytic inactivation of E. coli in aqueous suspensions
✍ Scribed by Catherine Drosou; Alberto Coz; Nikolaos P. Xekoukoulotakis; Armando Moya; Yolanda Vergara; Dionissios Mantzavinos
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Tongue
- English
- Weight
- 106 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0268-2575
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✦ Synopsis
Abstract
BACKGROUND: Although chlorination is an effective and widely employed method of water disinfection, it suffers serious drawbacks such as the formation of toxic chlorinated by‐products. Therefore, other disinfection technologies have been researched and developed, including advanced oxidation.
RESULTS: The efficacy of heterogeneous photocatalysis and sonophotocatalysis induced by UV‐A irradiation and low frequency (24–80 kHz) ultrasound irradiation in the presence of TiO~2~ as the photocatalyst and peracetic acid (PAA) as an additional disinfectant to inactivate E. coli in sterile water was evaluated. PAA‐assisted UV‐A/TiO~2~ photocatalysis generally leads to nearly complete E. coli inactivation in 10–20 min of contact time with the extent of inactivation depending on the photocatalyst type and loading (in the range 100–500 mg L^−1^) and PAA concentration (in the range 0.5–2 mg L^−1^). The simultaneous application of ultrasound and UV‐A irradiation in the presence of TiO~2~ and PAA prompted further E. coli inactivation.
CONCLUSIONS: The proposed advanced disinfection technology offers complete E. coli inactivation at short treatment times and low PAA doses. Copyright © 2010 Society of Chemical Industry
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