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Peptides of L- and D-Alanine. Synthesis and Optical Rotations *

✍ Scribed by Schechter, Israel; Berger, Arieh

Book ID: 127179265
Publisher: American Chemical Society
Year: 1966
Tongue: English
Weight: 797 KB
Volume: 5
Category: Article
ISSN: 0006-2960
DOI: 10.1021/bi00874a040

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## Abstract The title compound was prepared __via__ a malonic ester synthesis starting with α‐chloromethylpyrazine [2], and ending, after an asymmetric enzymatic hydrolysis of the racemic __N__‐acetyl‐β‐2‐pyrazinylalanine to the L‐form of the new amino acid. The optical purity was ascertained by ^1