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Peptide bond formation and subsequent hydrolysis at a cobalt(III) center

✍ Scribed by Buckingham, David A.; Marzilli, Luigi G.; Sargeson, Alan M.

Book ID: 126053788
Publisher: American Chemical Society
Year: 1967
Tongue: English
Weight: 247 KB
Volume: 89
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00987a069

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## Abstract Molecular‐orbital calculations have been performed for the conjugate base __cis__‐[Co(NH~3~)~4~(NH~2~)Cl]^+^ and __trans__‐[M(NH~3~)~4~(NH~2~)Cl]^+^ (M = Cr^III^, Co^III^, and Rh^III^), the hexacoordinated intermediates __cis‐__ and __trans__‐[Co(NH~3~)~4~(NH~2~)…Cl]^+^, the square‐pyra