Heterogeneous polyolefin catalysts based on metallocenium salts of weakly coordinating anions can be prepared via a series of simple reactions from lightly crosslinked chloromethylated polystyrene beads. Catalytic sites are distributed homogeneously throughout the polystyrene particles. The nonporou
✦ LIBER ✦
PEO-functionalized polystyrene as polymeric support in metallocene catalysed olefin polymerisation
✍ Scribed by Nikolay Nenov; Matthias Koch; Markus Klapper; Klaus Müllen
- Book ID
- 106002876
- Publisher
- Springer
- Year
- 2002
- Tongue
- English
- Weight
- 135 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0170-0839
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The Group 4 metallocene bis(enolate) complexes [Cp 2 M(-O-CMeCH 2 ) 2 ] (1) add one or two molar equivalents of the organometallic Lewis acid B(C 6 F 5 ) 3 to form the addition products (3), respectively. Complexes 3 a (M Ti) and 3 b (M Zr) were characterized by X-ray diffraction. Complexes 2 under