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Pentamethylcyclopentadienyl—Ruthenium Catalysts for Regio- and Enantioselective Allylation of Nucleophiles

✍ Scribed by Christian Bruneau; Jean-Luc Renaud; Bernard Demerseman


Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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Pentamethylcyclopentadienyl–Ruthenium Ca
✍ Christian Bruneau; Jean-Luc Renaud; Bernard Demerseman 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 374 KB

## Abstract Ruthenium(II) complexes containing the pentamethylcyclopentadienyl ligand efficiently perform the activation of allylic carbonates and halides to generate cationic and dicationic ruthenium(IV) complexes. This activation has been transferred as a key step to the catalytic allylation of n