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Pentamethylcyclopentadienyl-rhodium and -iridium complexes XV. Cationic complexes with tertiary phosphines and phosphites and their rearrangements reactions

✍ Scribed by Stephen J. Thompson; Colin White; Peter M. Maitlis


Book ID
108347357
Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
550 KB
Volume
136
Category
Article
ISSN
0022-328X

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## Abstract Mixed N‐heterocyclic carbene‐substituted phosphine and phosphite complexes of rhodium were prepared, starting from [Rh(COE)~2~Cl]~2~ (COE=cyclooctene) by addition of free N‐heterocyclic carbenes (NHC) and PR~3~. All new complexes were characterized by spectroscopy. In addition, the stru