Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part IX. The formation of η-allyl-MIII and η-diene-MI complexes from µ-hydrido-compounds and acyclic dienes

Formation of 18e− and 16e− Acyl(η3-cyclo

Formation of 18e− and 16e− Acyl(η3-cyclooctenyl)rhodium(III) Complexes in the Reaction of Cationic (Cycloocta-1,5-diene)rhodium(I) Compounds with 2-(Diphenylphosphino)benzaldehyde

✍ Rachad El Mail; María A. Garralda; Ricardo Hernández; Lourdes Ibarlucea; Elena P 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 137 KB 👁 1 views

The reaction of cationic diolefinic rhodium(I) complexes with 2-(diphenylphosphino)benzaldehyde (pCHO) was studied. [Rh(cod) 2 ]ClO 4 (cod cycloocta-1,5-diene) reacted with pCHO to undergo the oxidative addition of one pCHO with (1,2,3-h)cyclooct-2-en-1-yl (h 3 -C 8 H 13 ) formation, and the coordin