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Pentadentate Terpyridine−Catechol Linked Ligands and Their Cobalt(III) Complexes

✍ Scribed by Nagata, Toshi; Tanaka, Koji

Book ID
120057141
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
180 KB
Volume
39
Category
Article
ISSN
0020-1669

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Stereoselectivity in Reactions of Metal
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## Abstract The syntheses and characterization of four new linear pentadentate ligands and their Co^III^ complexes are described: __N__,__N__′‐[(pyridine‐2,6‐diy)bis(methylene)]bis[sarcosine] (sarmp), __N__,__N__′‐[(pyridine‐2,6‐diyl)bis(methylene)]bis[(__R__)‐ or (__S__)‐proline] ((__R__,__R__)‐ o

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## Abstract The synthesis of cobalt(III) complexes with the new linear pentadentate ligands meso‐ and racemic 2,6‐bis(3__S__)‐3‐carboxy‐4‐methyl‐2‐azapentylpyridine (**2**) are described. Only one of the different possible isomers is obtained from each ligand. The structure of the complexes has bee