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Pentacoordinated silicon anions: synthesis and reactivity

✍ Scribed by Brefort, Jean Louis; Corriu, Robert J. P.; Guerin, Christian; Henner, Bernard J. L.; Wong Chi Man, Wong Wee Choy

Book ID
120297919
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
817 KB
Volume
9
Category
Article
ISSN
0276-7333

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Two nutrients in one molecule: A zwitterionic Ξ»(5)Si,Ξ»(5)Si'-disilicate (1) was synthesized and characterized. It contains ligands that exclusively derive from natural products ((R,R)-tartaric acid, choline). Hydrolysis of 1 yields 2, which shows a remarkable kinetic stability in water. Upon dissolu