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Pentacoordinated molecules. 45. Molecular structure of the spirocyclic pentacoordinate indium(III) complex [(n-C4H9)4N]2{[S2C2(CN)2]2InCl} and the isomorphous thallium(III) complex [(n-C4H9)4N]2{[S2C2(CN)2]2TlBr}

✍ Scribed by Day, Roberta O.; Holmes, Robert R.


Book ID
126329875
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
494 KB
Volume
21
Category
Article
ISSN
0020-1669

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Dipole moments and polarisabilities are calculated by correlated methods for a series of linear molecules containing NN, CN and CC triple bonds. A compact polarised basis gives near-Hartree-Fock anisotropic polarisabilities with largest component along the molecular axis and roughly additive behavio