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PEMFC with improved poisoning tolerance using auxiliary stack

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
161 KB
Volume
2002
Category
Article
ISSN
1464-2859

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Asymmetric aziridination by reaction of
Asymmetric aziridination by reaction of chiral N-sulfinylimines with sulfur ylides: Stereoselectivity improvement by use of tert-butylsulfinyl group as chiral auxiliary
✍ JosΓ©L GarcΓ­a Ruano; Inmaculada FernΓ‘ndez; Miriam del Prado Catalina; Ana Alcudia πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 508 KB

Chiral tert-butylsulfinyl group has been shown to be the chiral auxiliary of choice for the asymmetric aziridination of N-sulfinyliminas. Moreover, the sense of the asymmetric induction can be tuned in two ways: the chirality at the tert-butylsulfinyl Sulfur, or the nature of the methylene transfer