Polarised infrared reflectivity spectra of some ET-based conducting salts of alpha-type structure are measured and compared: (ET) 2 I 3 (I), (ET) 2 TlHg(XCN) 4 (X ยค S,Se) (II) and (ET) 8 [Hg 4 Br 12 (CH 3 C 6 H 4 Cl) 2 ] (III). For both I and II the electronic reflectivity is greater for the polaris
โฆ LIBER โฆ
Peculiarties of the electronic and electron vibrational spectra of organic conductors: BEDT-TTF salts of alpha-type structure
โ Scribed by M. G. Kaplunov; N. D. Kushch; R. N. Lyubovskaya
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 302 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1616-301X
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Bromohexyl)-3ยข,4ยข-ethylenedioxy)-2,2ยข-bithiophene (3): Into a roundbottomed flask were introduced EDOT (5.9 g, 41.4 mmol) and 150 mL of tetrahydrofuran (THF). The mixture was cooled to ยฑ40 C and butyllithium, 2.5 M in hexanes (19 mL, 47.5 mmol), was added rapidly. After 1 h stirring, tributyltin chl