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Peculiar Structures of Small Magnesium Carbide Clusters: MgC 2 , (MgC 2 ) 2 , and (MgC 2 ) 4

✍ Scribed by Boldyrev, Alexander I.; Simons, Jack

Book ID
126791691
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
96 KB
Volume
101
Category
Article
ISSN
1089-5639

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The T1 and T2 crystalline varieties of the ternary carbide AI2MgC2 were synthesized by reacting graphite particles with Mg-AI melts at 930-1020 K. Below 1000 K, the TI variety was predominant but little amounts of 1"2 were also preseat. At 1000K and above, only the T2 variety was obtained. Assuming