Peculiar Sharpless kinetic resolution of 2-furylmethanol and its application to the synthesis of (+)-Asperlin
β Scribed by Zhi-Cai Yang; Wei-Shan Zhou
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 106 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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Kinetic resolution of racemic l-cyano-l-methylalkyl and alkenyl acetates has been achieved on incubation with Pichia mist IAM 4682, which -hydrolyzed selectively the (RI-enantianer, leaving behind the (S)-enantianer intact. The chiral l-cyano-lmethyl-5-hexenyl acetate thus obtained was converted to
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