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Peak suppression in Fourier transform n.m.r.: Application of the selective excitation technique to the problem of 13C satellites in 31P resonance

✍ Scribed by R. K. Harris; R. H. Newman; A. Okruszek


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
258 KB
Volume
9
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

Selective pulsed excitation was used in a technique to suppress the resonance due to a per‐^12^C‐isotopomer so as to overcome dynamic range problems when observing ‘^13^C satellite’ lines. The technique was used to obtain nuclear spin parameters from the ^13^C satellites in ^31^P resonance for the racemic isomer of P,P′‐dimethyl‐P,P′‐diphenyldiphosphine disulphide, [MePhP(:S)]~2~.