Pd(II) complexes of amino alcohols and their reaction with chloramine-T: A kinetic study

✍ Scribed by Anju Shukla; Sushma Gupta; Santosh K. Upadhyay

• Publisher: John Wiley and Sons
• Year: 1991
• Tongue: English
• Weight: 486 KB
• Volume: 23
• Category: Article
• ISSN: 0538-8066
• DOI: 10.1002/kin.550230402

✦ Synopsis

Abstract

The kinetics of reaction of amino alcohols viz. 2‐aminoethanol, 3‐aminopropanol, and triethanolamine with chloramine‐T have been studied in perchloric acid medium with palladous chloride as catalyst. The formation of {Pd(II)‐(aminoalcohol)} and {Pd(II)‐(aminoalcohol)~2~} complexes and resistance of {Pd(II)‐(aminoalcohol)~2~} complex to react with chloramine‐T have been observed. A suitable mechanism consistent with the kinetic data is proposed and discussed.