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PdII-Catalyzed Oxidative 1,1-Diarylation of Terminal Olefins

✍ Scribed by Werner, Erik W.; Urkalan, Kaveri B.; Sigman, Matthew S.


Book ID
115487494
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
345 KB
Volume
12
Category
Article
ISSN
1523-7060

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## Abstract Various 1,3‐diaryl‐2‐arylethynyl‐1,3‐butadienes **7** have been prepared by the Pd‐catalyzed trimerization of arylalkynes **4**. Their structures and stereochemistry have been confirmed by X‐ray crystal analyses. This procedure provides high regioselectivity to generate adducts __Z__‐**