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PdII-Catalyzed Cyclization of Alkynes Containing Aldehyde, Ketone, or Nitrile Groups Initiated by the Acetoxypalladation of Alkynes

✍ Scribed by Ligang Zhao; Xiyan Lu


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
78 KB
Volume
114
Category
Article
ISSN
0044-8249

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The novel nickel(II)-and palladium(II) complexes (box)Ni(acac) 2 (1), (box)Ni(mes)(Br) (2), (box)Pd(mes) 2 (3), [(PEMA)NiBr]Br (4 a) and [(PEMA)PdCl]Cl (4 b) were synthesized and investigated by IR-, MS-and (except the paramagnetic compound 1) by NMR spectroscopy (box: 4,4,4',4'-tetramethyl-2,2'-bis