PdCl2-Catalyzed Two-Component Cross-Coupling Cyclization of 2,3-Allenoic Acids with 2,3-Allenols. An Efficient Synthesis of 4-(1′,3′-Dien-2′-yl)-2(5H)-furanone Derivatives.
✍ Scribed by Shengming Ma; Zhenhua Gu
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 29 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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## Abstract Transition‐metal‐catalyzed dimeric coupling–cyclization reactions of two different 2,3‐allenols afforded 4‐(1′,3′‐dien‐2′‐yl)‐2,5‐dihydrofuran derivatives **3**. 2‐Substituted 2,3‐allenols **1** cyclized to form the 2,5‐dihydrofuran ring, whereas the 2‐unsubstituted 2,3‐allenols **2** p
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