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Pd/C-Catalyzed Transfer-Hydrogenation of Benzaldehydes to Benzyl Alcohols Using Potassium Formate as the Selective Hydrogen Donor.

โœ Scribed by Mubeen Baidossi; Ashutosh V. Joshi; Sudip Mukhopadhyay; Yoel Sasson


Publisher
John Wiley and Sons
Year
2004
Weight
122 KB
Volume
35
Category
Article
ISSN
0931-7597

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๐Ÿ“œ SIMILAR VOLUMES


Highly selective transfer hydrogenation
โœ G. Cavinato; L. Toniolo ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 478 KB

A Pd/C catalytic system is highly active and selective at 8040ยฐC in the hydrogen transfer reaction from sodium formate to the C=C double bond of PhCOCH=CHCOOH to yield the corresponding y-keto acid PhCOCH,CH,COOH. When the substrate is allowed to react with a defect of formate salt and in the presen