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Pd0-Catalyzed Coupling Cyclization Reaction of Aryl or 1Alkenyl Halides with 1,2-Allenyl Ketones: Scope and Mechanism. An Efficient Assembly of 2,3,4-, 2,3,5-Tri- and 2,3,4,5-Tetrasubstituted Furans

✍ Scribed by Shengming Ma; Junliang Zhang; Lianghua Lu

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 227 KB
Volume: 9
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.200204664

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## Abstract magnified image Described herein is the development of a palladium(II)‐catalyzed two‐ or three‐component reaction of 2‐(1‐alkynyl)‐2‐alken‐1‐ones with nucleophiles and allylic chlorides. Various types of nucleophiles such as __O‐__, __N‐__, __C__‐based nucleophiles and olefin‐tethered