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Pd-Catalyzed Nucleophilic Alkylation of Aliphatic Aldehydes with Allyl Alcohols: Allyl, 2-Tetrahydrofuryl, and 2-Tetrahydropyranyl Ethers as Useful C3, C4, and C5 Sources

✍ Scribed by Masanari Kimura; Masamichi Shimizu; Kazufumi Shibata; Minoru Tazoe; Yoshinao Tamaru

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 130 KB
Volume: 42
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200351182

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Pd-Catalyzed Nucleophilic Alkylation of

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✍ Masanari Kimura; Masamichi Shimizu; Kazufumi Shibata; Minoru Tazoe; Yoshinao Tam 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 130 KB 👁 2 views

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## Abstract Palladium–diethylzinc or palladium–triethylborane catalytically promotes self‐allylation of 2‐(allyloxy)tetrahydrofurans, 2‐(allyloxy)tetrahydropyrans, and their hydroxy derivatives on the rings (ribose, glucose, mannose, deoxyribose, deoxyglucose). All the reactions proceed at room tem