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Pd-Catalyzed Enantioselective Aerobic Oxidation of Secondary Alcohols: Applications to the Total Synthesis of Alkaloids

โœ Scribed by Krishnan, Shyam; Bagdanoff, Jeffrey T.; Ebner, David C.; Ramtohul, Yeeman K.; Tambar, Uttam K.; Stoltz, Brian M.


Book ID
115458848
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
736 KB
Volume
130
Category
Article
ISSN
0002-7863

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The securinega alkaloids are a family of approximately 20 tetracyclic compounds produced by several Securinega and Phyllanthus species of the Euphorbiaceae plant family. The major securinega alkaloid is securinine (1), isolated from the leaves of Securinega suffruticosa. Its enantiomer, virosecurin